Materials/Polymers/Polyimides

Kapton H

misse2-pi-kapton-h

In short

On the International Space Station's forward-facing side, oxygen atoms ate away 253 µm of Kapton H in 3.95 years, about 64 µm a year. A standard 25 µm film of it would last about 5 months there. Kapton H is the reference film that other materials are compared with.

Benchmarks

The benchmarks that matter for this material's applications, each compared with the reference engineers use.

BenchmarkResultCompared with reference
Atomic oxygen erosionHow fast low-orbit oxygen eats the surface. Lower is better. 3.00×10⁻²⁴ cm³/atomLow Earth orbit, 3.95 years in flight 1.00× Kapton HThis is the reference film

Not measured yet (5): darkening under UV and particles (Δα); outgassing, total mass loss (TML); outgassing, condensable (CVCM); thermal cycling survival; flammability (crewed vehicles).

Applications

Where materials like Kapton H are considered, the benchmarks that decide each use, and what the measured data says so far.

ApplicationDeciding benchmarksWhat the data says
External surfaces in low Earth orbit1 of 2 deciding benchmarks measured
  • Atomic oxygen erosion
  • Darkening under UV and particles (Δα)
Reference film: unprotected, 25 µm lasts about 5 months on forward-facing low-orbit surfaces. Still needed: darkening under UV and particles (Δα).
Thermal blankets (MLI) outer layer1 of 4 deciding benchmarks measured
  • Atomic oxygen erosion
  • Darkening under UV and particles (Δα)
  • Outgassing, total mass loss (TML)
  • Outgassing, condensable (CVCM)
Reference film: unprotected, 25 µm lasts about 5 months on forward-facing low-orbit surfaces. Still needed: darkening under UV and particles (Δα); outgassing, total mass loss (TML); outgassing, condensable (CVCM).

"What the data says" is Space Mushroom's reading of the measured values, not a flight qualification. Deciding benchmarks come from the Benchmark Framework.

What it went through

WhereISS, MISSE 2, PEC 2 tray 1 (outside the Quest airlock)
When2001-08-16 to 2005-07-30 (3.95 years)
Atomic oxygen dose8.43×10²¹ atoms/cm²
Sunlight5,000–6,700 equivalent sun hours
TemperatureCycled between −30 °C and 40 °C
Also exposed toSolar UV and charged particle radiation, in vacuum

How it compares

Materials flown on the same tray, ranked from least to most eroded. Kapton H is number 25 of 40.

RankMaterialCompared with Kapton HLost in 3.95 years
5 FEPFluorinated ethylene propylene 0.067× 17 µm
23 PSUPolysulphone 0.98× 248 µm
24 PEEKPolyetheretherketone 1.00× 252 µm
25 Kapton HPolyimide (PMDA) 1.00× 253 µm
26 MylarPolyethylene terephthalate 1.00× 254 µm
27 PMR-15High temperature polyimide resin >1.01× >255 µm

How the numbers are calculated

  • Erosion yield is NASA's measurement: volume of material removed per oxygen atom.
  • Thickness lost = erosion yield × oxygen dose = 3.00×10⁻²⁴ cm³/atom × 8.43×10²¹ atoms/cm² = 0.0253 cm = 253 µm.
  • Compared with Kapton H = erosion yield ÷ 3.00×10⁻²⁴ (Kapton H's value on the same flight).
  • Film life = 25 µm ÷ 64 µm per year, for the same exposure.