Materials/Polymers/Polycarbonates

PC

misse2-pc

In short

On the International Space Station's forward-facing side, oxygen atoms ate away 362 µm of PC in 3.95 years, about 92 µm a year. A standard 25 µm film of it would last about 3 months there. It erodes 1.4 times faster than Kapton H, the reference film.

Benchmarks

The benchmarks that matter for this material's applications, each compared with the reference engineers use.

BenchmarkResultCompared with reference
Atomic oxygen erosionHow fast low-orbit oxygen eats the surface. Lower is better. 4.29×10⁻²⁴ cm³/atomLow Earth orbit, 3.95 years in flight 1.43× Kapton HErodes 1.4× faster

Not measured yet (3): darkening under UV and particles (Δα); outgassing, total mass loss (TML); thermal cycling survival.

Applications

Where materials like PC are considered, the benchmarks that decide each use, and what the measured data says so far.

ApplicationDeciding benchmarksWhat the data says
External surfaces in low Earth orbit1 of 2 deciding benchmarks measured
  • Atomic oxygen erosion
  • Darkening under UV and particles (Δα)
Atomic oxygen resistance is poor (1.43×): unprotected, it wears through quickly on forward-facing low-orbit surfaces and would need a protective coating. Still needed: darkening under UV and particles (Δα).

"What the data says" is Space Mushroom's reading of the measured values, not a flight qualification. Deciding benchmarks come from the Benchmark Framework.

What it went through

WhereISS, MISSE 2, PEC 2 tray 1 (outside the Quest airlock)
When2001-08-16 to 2005-07-30 (3.95 years)
Atomic oxygen dose8.43×10²¹ atoms/cm²
Sunlight5,000–6,700 equivalent sun hours
TemperatureCycled between −30 °C and 40 °C
Also exposed toSolar UV and charged particle radiation, in vacuum

How it compares

Materials flown on the same tray, ranked from least to most eroded. PC is number 34 of 40.

RankMaterialCompared with Kapton HLost in 3.95 years
5 FEPFluorinated ethylene propylene 0.067× 17 µm
25 Kapton HPolyimide (PMDA) 1.00× 253 µm
32 PSPolystyrene 1.25× 315 µm
33 EPEpoxide or epoxy 1.40× 355 µm
34 PCPolycarbonate 1.43× 362 µm
35 CACellulose acetate 1.68× 426 µm
36 PMMAPolymethyl methacrylate >1.87× >472 µm

How the numbers are calculated

  • Erosion yield is NASA's measurement: volume of material removed per oxygen atom.
  • Thickness lost = erosion yield × oxygen dose = 4.29×10⁻²⁴ cm³/atom × 8.43×10²¹ atoms/cm² = 0.0362 cm = 362 µm.
  • Compared with Kapton H = erosion yield ÷ 3.00×10⁻²⁴ (Kapton H's value on the same flight).
  • Film life = 25 µm ÷ 92 µm per year, for the same exposure.