Materials/Polymers/Fluoropolymers
Kynar
misse2-pvdf-kynarIn short
On the International Space Station's forward-facing side, oxygen atoms ate away 109 µm of Kynar in 3.95 years, about 28 µm a year. A standard 25 µm film of it would last about 11 months there. It resists atomic oxygen 2.3 times better than Kapton H, the reference film.
Benchmarks
The benchmarks that matter for this material's applications, each compared with the reference engineers use.
| Benchmark | Result | Compared with reference |
|---|---|---|
| Atomic oxygen erosionHow fast low-orbit oxygen eats the surface. Lower is better. | 1.29×10⁻²⁴ cm³/atomLow Earth orbit, 3.95 years in flight | 0.43× Kapton HResists 2.3× better |
Not measured yet (7): darkening under UV and particles (Δα); outgassing, total mass loss (TML); outgassing, condensable (CVCM); solar absorptance (α); thermal emittance (ε); thermal cycling survival; flammability (crewed vehicles).
Applications
Where materials like Kynar are considered, the benchmarks that decide each use, and what the measured data says so far.
| Application | Deciding benchmarks | What the data says |
|---|---|---|
| External surfaces in low Earth orbit1 of 2 deciding benchmarks measured |
| Atomic oxygen resistance is good (0.43×). Still needed: darkening under UV and particles (Δα). |
| Thermal blankets (MLI) outer layer1 of 4 deciding benchmarks measured |
| Atomic oxygen resistance is good (0.43×). Still needed: darkening under UV and particles (Δα); outgassing, total mass loss (TML); outgassing, condensable (CVCM). |
| Radiators and thermal coatings0 of 3 deciding benchmarks measured |
| None of the deciding benchmarks are measured yet. Side check: atomic oxygen resistance is good (0.43×). |
"What the data says" is Space Mushroom's reading of the measured values, not a flight qualification. Deciding benchmarks come from the Benchmark Framework.
What it went through
| Where | ISS, MISSE 2, PEC 2 tray 1 (outside the Quest airlock) |
|---|---|
| When | 2001-08-16 to 2005-07-30 (3.95 years) |
| Atomic oxygen dose | 8.43×10²¹ atoms/cm² |
| Sunlight | 5,000–6,700 equivalent sun hours |
| Temperature | Cycled between −30 °C and 40 °C |
| Also exposed to | Solar UV and charged particle radiation, in vacuum |
How it compares
Materials flown on the same tray, ranked from least to most eroded. Kynar is number 11 of 40.
| Rank | Material | Compared with Kapton H | Lost in 3.95 years |
|---|---|---|---|
| 5 | FEPFluorinated ethylene propylene | 0.067× | 17 µm |
| 9 | TefzelTetrafluoroethylene-ethylene copolymer | 0.32× | 81 µm |
| 10 | ABSAcrylonitrile butadiene styrene | 0.36× | 92 µm |
| 11 | KynarPolyvinylidene fluoride | 0.43× | 109 µm |
| 12 | ZylonPoly(p-phenylene-2 6-benzobisoxazole) | 0.45× | 115 µm |
| 13 | PANPolyacrylonitrile | 0.47× | 119 µm |
| 25 | Kapton HPolyimide (PMDA) | 1.00× | 253 µm |
How the numbers are calculated
- Erosion yield is NASA's measurement: volume of material removed per oxygen atom.
- Thickness lost = erosion yield × oxygen dose = 1.29×10⁻²⁴ cm³/atom × 8.43×10²¹ atoms/cm² = 0.0109 cm = 109 µm.
- Compared with Kapton H = erosion yield ÷ 3.00×10⁻²⁴ (Kapton H's value on the same flight).
- Film life = 25 µm ÷ 28 µm per year, for the same exposure.
Full record
The complete spore, as stored. Free to reuse under CC-BY-4.0.
spore: passport
id: misse2-pvdf-kynar
spore_version: 0.1
status: measured
org: nasa
dataset: misse2-peace
material:
name: "Polyvinylidene fluoride"
abbreviation: "PVDF (Kynar)"
family: Fluoropolymer
category: polymers
type: fluoropolymers
tags:
environments: [low-earth-orbit]
stresses: [atomic-oxygen, uv, total-radiation-dose, thermal-cycling, vacuum-and-outgassing]
applications: []
exposures:
- environment: low Earth orbit
platform: ISS, MISSE 2, PEC 2 tray 1 (outside the Quest airlock)
start: 2001-08-16
end: 2005-07-30
duration_years: 3.95
atomic_oxygen_fluence: {value: 8.43e21, unit: atoms/cm2}
solar_exposure: {value: "5000-6700", unit: equivalent sun hours}
thermal_cycling: {min_c: -30, max_c: 40, note: nominal base-plate range}
results:
- property: atomic oxygen erosion yield
value: 1.29e-24
unit: cm3/atom
lower_bound: false
sources:
- title: Atomic Oxygen Erosion Yield Predictive Tool for Spacecraft Polymers in Low Earth Orbit
id: NASA/TM-2008-215490 (Banks, Backus and de Groh, December 2008)
url: https://ntrs.nasa.gov/citations/20090011780
where: Table I; exposure details in section 2.1
license: CC-BY-4.0
Sources
- Atomic Oxygen Erosion Yield Predictive Tool for Spacecraft Polymers in Low Earth Orbit. NASA/TM-2008-215490 (Banks, Backus and de Groh, December 2008), Table I; exposure details in section 2.1.